刘辉,杨晓,付文才,党文豪,王志伟.OCC造纸废水中微细胶黏物及Ca2+协同去除的研究[J].中国造纸学报,2021,36(3):54-60 本文二维码信息
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OCC造纸废水中微细胶黏物及Ca2+协同去除的研究
Study on the Synergistic Removal of Micro-stickies and Ca2+ from OCC Wastewater
投稿时间:2021-07-14  
DOI:10.11981/j.issn.1000-6842.2021.03.54
中文关键词:  OCC造纸废水  微细胶黏物  电絮凝  Ca2+  絮凝体
Key Words:OCC papermaking wastewater  micro-stickies  electrocoagulation  Ca2+  floc
基金项目:国家自然科学基金(21868004);广西重点研发计划项目(桂科AB19259013)。
作者单位邮编
刘辉 广西大学轻工与食品工程学院广西南宁530004
广西清洁制浆造纸与污染控制重点实验室广西南宁530004 
530004
杨晓 广西大学轻工与食品工程学院广西南宁530004
广西清洁制浆造纸与污染控制重点实验室广西南宁530004 
530004
付文才 广西大学轻工与食品工程学院广西南宁530004
广西清洁制浆造纸与污染控制重点实验室广西南宁530004 
530004
党文豪 广西大学轻工与食品工程学院广西南宁530004
广西清洁制浆造纸与污染控制重点实验室广西南宁530004 
530004
王志伟 广西大学轻工与食品工程学院广西南宁530004
广西清洁制浆造纸与污染控制重点实验室广西南宁530004 
530004
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中文摘要:
      废旧箱纸板(OCC)造纸废水回用过程中面临着微细胶黏物沉积和因Ca2+浓度过高引起的厌氧颗粒污泥钙化两大难题。本研究对比评估了电絮凝法、物理法、化学法、生物酶法对模拟OCC造纸废水的处理效果;结果表明,电絮凝法能够更好去除OCC造纸废水中的微细胶黏物和Ca2+。在此基础上研究了电絮凝处理的最佳条件:铝为阳极材料,电流密度、电极间距和反应时间的最佳处理条件分别为115 A/m2、5 cm和60 min。在最佳条件下,经电絮凝处理后得到的絮凝体中,Al3+和Ca2+的相对含量高于对照组,表明电絮凝法能有效去除OCC造纸废水中的微细胶黏物、COD和Ca2+,且该方法绿色无污染,符合可持续发展的要求。
Abstract:
      There are two problems in the reusing process of OCC papermaking wastewater, i.e., the deposition of micro stickies and the calcification of anaerobic granular sludge caused by high Ca2+ concentration. The effects of electrocoagulation, physical, chemical, and biological enzymatic treatments towards OCC papermaking wastewater were compared in this study. The results showed that the electrocoagulation treatment could remove more micro-stickies and Ca2+ compared with other methods. The optimal conditions of electrocoagulation treatment were further explored: aluminum used as the anode, the current density, electrode distance, and reaction time were 115 A/m2, 5 cm, and 60 min, respectively. The relative contents of Al3+ and Ca2+ in flocs after electrocoagulation treatment (under the optimum conditions) were higher than those in the control group, indicating that the micro-stickies, COD, and Ca2+ in OCC wastewater were removed by electrocoagulation effectively, which is a green and non-pollutant process conforming to the requirements of sustainable development.
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