李思齐,陆赵情,贾峰峰,花莉,徐明源,黄涛,赵会媚.芳纶纤维/分子筛纸基过滤材料的制备及其过滤性能研究[J].中国造纸学报,2025,(2):103-111 |
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芳纶纤维/分子筛纸基过滤材料的制备及其过滤性能研究 |
Study on the Preparation of Aramid Fiber/Molecular Sieve Paper-based Filtration Material and Its Filtration Properties |
投稿时间:2024-03-10 修订日期:2024-03-27 |
DOI:10.11981/j.issn.1000-6842.2025.02.103 |
中文关键词: 芳纶纤维 分子筛 过滤效率 吸附特性 |
Key Words:aramid fiber molecular sieve filtering efficiency adsorption characteristics |
基金项目:国家自然科学基金(22378248);陕西省秦创原“科学家+工程师”队伍建设(2023KXJ-211);陕西省技术创新引导专项(基金)(2023GXLH-077);龙游县科学技术局重大科技攻关课题(JHXM2022140);陕西省军民融合专项(陕融办发[2024]22号);国家级大学生创新创业训练计划资助项目(202310708007);省级大学生创新创业训练计划资助项目(202410708116)。 |
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中文摘要: |
通过DMSO/KOH/H2O体系对对位芳纶浆粕表面进行活化处理,复合间位芳纶沉析纤维后,共同作为三维支撑骨架,并以4A型分子筛为吸附剂,通过湿法成形,制得芳纶纤维/分子筛纸基过滤材料。结果表明,当对位芳纶浆粕、间位芳纶沉析纤维质量及比例不变,分子筛添加量为1.5 g时,芳纶纤维/分子筛纸基过滤材料综合性能最佳,断裂应力为8 MPa,透气度6 μm/(Pa·s),对PMs和甲醛的去除率分别达99.99%和93.17%。 |
Abstract: |
Using para-aramid pulp/meta-aramid precipitated fiber as the three-dimensional supporting skeleton, of which the para-aramid pulp surface was activated by the DMSO/KOH/H2O system, and 4A type molecular sieve as the adsorbent, the aramid fiber/molecular sieve paper-based materials were prepared via wet forming by compounding para-aramid pulp, meta-aramid precipitated fiber and molecular sieve. The results showed that when the mass ratio of para-aramid pulp, meta-aramid precipitated fiber did not be changed, and molecular sieve additive amount was 1.5 g, the prepared aramid fiber/molecular sieve paper-based material had the best comprehensive performance, with breaking stress of 8 MPa, air permeability of 35 μm/(Pa·s), and removal rate towards PMs and formaldehyde of 99.99% and 93.17%, respectively. |
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