张东阳,乔义超,王汉敏,侯庆喜,司传领.木质素基硬碳材料的制备及其在钠离子电池中的应用研究进展[J].中国造纸学报,2025,40(3):106-120 本文二维码信息
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木质素基硬碳材料的制备及其在钠离子电池中的应用研究进展
Research Progress in Preparation of Lignin-based Hard Carbon Materials and Its Application in Sodium Ion Batteries
投稿时间:2025-04-14  修订日期:2025-04-24
DOI:10.11981/j.issn.1000-6842.2025.03.106
中文关键词:  木质素  硬碳材料  复合改性  钠离子电池  电化学性能
Key Words:lignin  hard carbon materials  compound modification  sodium ion battery  electrochemical performance
基金项目:国家自然科学基金青年项目(22208248)。
作者单位邮编
张东阳* 天津科技大学生物基纤维材料全国重点实验室天津市制浆造纸重点实验室中国轻工业造纸与生物质精炼重点 实验室天津300457 300457
乔义超 天津科技大学生物基纤维材料全国重点实验室天津市制浆造纸重点实验室中国轻工业造纸与生物质精炼重点 实验室天津300457 300457
王汉敏* 天津科技大学生物基纤维材料全国重点实验室天津市制浆造纸重点实验室中国轻工业造纸与生物质精炼重点 实验室天津300457 300457
侯庆喜 天津科技大学生物基纤维材料全国重点实验室天津市制浆造纸重点实验室中国轻工业造纸与生物质精炼重点 实验室天津300457 300457
司传领 天津科技大学生物基纤维材料全国重点实验室天津市制浆造纸重点实验室中国轻工业造纸与生物质精炼重点 实验室天津300457 300457
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中文摘要:
      本文介绍了木质素的结构与特性,阐述其作为钠离子电池硬碳材料前驱体的优势;总结了木质素基硬碳材料的制备方法,包括预处理方法、碳化过程及后续改性策略等;并基于木质素的结构和制备工艺,探讨了木质素基硬碳材料电化学性能提升的优化方法,同时综述了木质素基硬碳材料在钠离子电池中的应用研究进展,以及目前该类材料在实际应用中面临的挑战。最后,对未来推动木质素基硬碳材料在钠离子电池领域的大规模应用提出展望。
Abstract:
      In this paper, the structure and characteristics of lignin were introduced, and its advantages as a precursor of hard carbon materials for sodium ion batteries were expounded. The preparation methods of lignin-based hard carbon materials were summarized in detail, including pretreatment methods, carbonization process and subsequent modification strategies. In addition, based on the structure and preparation process of lignin, the optimization methods of the electrochemical properties improvement of carbon materials were discussed, and the application research progress of lignin-based carbon materials in sodium ion batteries was summarized, as well as the challenges faced by this kind of materials in practical application at present. Finally, the prospect of promoting the large-scale application of lignin-based hard carbon materials in the field of sodium ion batteries in the future was put forward.
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