姜皓明,黄吉振,刘玉新,刘梦雨,李凯.芳纶纳米纤维/氮化硼纳米片复合纸的微溶解机理研究[J].中国造纸学报,2025,40(4):93-100 本文二维码信息
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芳纶纳米纤维/氮化硼纳米片复合纸的微溶解机理研究
Study on Micro-dissolution Mechanism of Aramid Nanofiber/Boron Nitride Nanosheet Composite Paper
投稿时间:2024-10-08  修订日期:2024-11-05
DOI:10.11981/j.issn.1000-6842.2025.04.93
中文关键词:  芳纶  芳纶纳米纤维  氮化硼纳米片  复合纸  微溶解
Key Words:aramid  aramid nanofiber  boron nitride nanosheet  composite paper  micro-dissolution
基金项目:云南省教育厅可降解塑料工程研究中心(KKPU202205001);云南省中青年学术和技术带头人后备人才(202305AC160061)。
作者单位邮编
姜皓明* 昆明理工大学化学工程学院云南昆明650500 650500
黄吉振* 昆明理工大学化学工程学院云南昆明650500 650500
刘玉新* 昆明理工大学化学工程学院云南昆明650500
云南省教育厅教学塑料工程研究中心云南昆明650000 
650000
刘梦雨 昆明理工大学化学工程学院云南昆明650500 650500
李凯 昆明理工大学化学工程学院云南昆明650500 650500
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中文摘要:
      本研究以二甲基亚砜(DMSO)/H2O/KOH为溶剂,对芳纶纳米纤维(ANF)/氮化硼纳米片(BNNS)复合纸进行溶解,研究不同BNNS质量分数的ANF/BNNS复合纸的溶解速率差别,探究ANF/BNNS复合纸的微溶解规律。结果表明,纯ANF纸的拉伸强度为48.8 MPa,从25 ℃升高至70 ℃所需时间为6 s,溶解厚度为42.0 μm,而ANF/BNNS复合纸(BNNS质量分数20%)的拉伸强度降低至34.5 MPa,从25 ℃升高至70 ℃仅需2 s,溶解时间为3 h,溶解厚度为52.5 μm,较纯ANF纸的溶解厚度提升了25%,表明BNNS的加入会略微降低ANF/BNNS复合纸的机械强度,显著提升ANF/BNNS复合纸的导热性能,并促进ANF/BNNS复合纸的溶解。
Abstract:
      In this study, DMSO/H2O/KOH was used as the solvent to dissolve aramid nanofiber (ANF)/boron nitride nanosheet (BNNS) composite paper, to study the difference in the dissolution rate of ANF/BNNS composite paper with different BNNS contents, and to investigate the micro-dissolution law of ANF/BNNS composite paper. The results showed that the tensile strength of pure ANF paper was 48.8 MPa, the time required to increase from 25 ℃ to 70 ℃ was 6 s, and the dissolution thickness was 42.0 μm, while the tensile strength of ANF/BNNS composite paper with BNNS content of 20% was reduced to 34.5 MPa, and the time required to increase from 25 ℃ to 70 ℃ was only 2 s. The dissolution time was 3 h, and the dissolution thickness was 52.5 μm, which was 25% more than that of pure ANF paper. It was indicated that the addition of BNNS slightly reduced the mechanical strength of the ANF/BNNS composite paper, significantly improved the thermal conductivity of the ANF/BNNS composite paper, promoted the dissolution of the ANF/BNNS composite paper.
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