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Synthesis and Application of Starch Grafted with Polyurethane Prepolymer
  
DOI:10.11981/j.issn.1000-6842.2011.02.33
Key Words:polyurethane prepolymer; graft; starch; sizing
Fund Project:本项目为国家自然科学基金(20776055)资助。
Author NameAffiliation
陈夫山 青岛科技大学化工学院,山东青岛,266042 
赵 华 青岛科技大学化工学院,山东青岛,266042 
宋晓明 青岛科技大学化工学院,山东青岛,266042 
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Abstract:
      Polyurethane-based grafted starch is a new type of surface sizing agent in recent years. In this paper, polyurethane prepolymer was used as a special water-resisant monomer, polyurethane-based grafted starch agent with good performance was synthesized. The better synthesis conditions of prepolymer were as follows: The amount of toluene di-isocyanate is 15% of 1,4-butanediol, the temperature is 80℃. The optimal synthesis conditions of the sizing agent were as follows: the amount of prepolymer is 10% (on starch), the weight ratio of monomer to starch is 2∶1, the weight ratio of styene to butyl acrylate is 1.5∶1.
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