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Enzymatic Pretreated Starch Oxidized by TEMPO/NaBr/NaClO System and Its Application in Surface Sizing
  
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Key Words:starch; enzymatic hydrolysis; TEMPO oxidation; surface sizing
Fund Project:国家自然科学基金项目(30871955);江苏高校优势学科建设工程资助项目(PAPD)。
Author NameAffiliation
张玉娟 南京林业大学江苏省制浆造纸科学与技术重点实验室,江苏南京,210037 
戴红旗* 南京林业大学江苏省制浆造纸科学与技术重点实验室,江苏南京,210037 
李媛媛 南京林业大学江苏省制浆造纸科学与技术重点实验室,江苏南京,210037 
毛圣陶 南京林业大学江苏省制浆造纸科学与技术重点实验室,江苏南京,210037 
王晶晶 南京林业大学江苏省制浆造纸科学与技术重点实验室,江苏南京,210037 
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Abstract:
      Corn starch enzymatic hydrolysis was carried out by using α-amylase, after enzymatic treatment, the starch was further oxidized by TEMPO oxidation system, then, the product was used for surface sizing. The experiment results indicated that the most efficient reaction condition of TEMPO system oxidation was as follows, pH value was 9.5, temperature was 5℃, reaction time was 2.0 h, dosage of TEMPO was 1.0 mg/g and the dosage of NaClO was 2.00 mmol/g. In this condition, the modified starch had 5.06% of the carboxyl contents. Using the starch as surface sizing agent and with the sizing dosage of 4 g/m2, tensile strength and surface strength of sized sheet rose by 51.6% and 334% compared with the sheets without sizing.
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