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Kinetic Model of Hemicellulose Dissolution during Water Prehydrolysis of Phyllostachys Heterocyclava |
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Key Words:phyllostachys heterocyclava; water prehydrolysis; pentosan; kinetics |
Author Name | Affiliation | 谭丽红1 | 1.长沙理工大学化学与生物工程学院,湖南长沙,410114 | 马乐凡1 | 1.长沙理工大学化学与生物工程学院,湖南长沙,410114 | 刘定军2 | 2.会同宝庆恒达纸业有限公司,湖南怀化,418300 | 刘继权2 | 2.会同宝庆恒达纸业有限公司,湖南怀化,418300 | 曾 凯1 | 1.长沙理工大学化学与生物工程学院,湖南长沙,410114 | 梁宇婷1 | 1.长沙理工大学化学与生物工程学院,湖南长沙,410114 |
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Abstract: |
Kinetic model of hemicellulose dissolution during water prehydrolysis of phyllostachys heterocyclava under the conditions of temperature 140~170℃, reaction time of the temperature 0~300 min and ratio of liquid to solid 10∶1 was studied. All experimental data were fitted to get the kinetic parameters. The results showed that the hydrolysis reaction of hemicellulose was clearly divided into fast and slow stages from 140℃ to 170℃, the activation energys were 83.29 kJ/mol and 138.79 kJ/mol respectively. The reaction temperature had significant influence on the water prehydrolysis process, which must be strictly controlled to achieve the purpose of removing hemicellulose in a short time and reducing the degradation of cellulose. |
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