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Synthesis of Lightly Cross-linked Amphoteric Polyacrylamide and Its Application as Paper Strengthening Agent
  
DOI:10.11981/j.issn.1000-6842.2016.02.7
Key Words:amphoteric polyacrylamide; lightly cross-linked; paper strengthening agent
Fund Project:制浆造纸国家工程实验室博士基金项目。
Author NameAffiliation
毛 萃1,2 1.中国制浆造纸研究院,北京,100102;2.制浆造纸国家工程实验室,北京,100102 
万 莹1,2 1.中国制浆造纸研究院,北京,100102;2.制浆造纸国家工程实验室,北京,100102 
孟凡锦1,2 1.中国制浆造纸研究院,北京,100102;2.制浆造纸国家工程实验室,北京,100102 
刘群华1,2 1.中国制浆造纸研究院,北京,100102;2.制浆造纸国家工程实验室,北京,100102 
刘 文1,2 1.中国制浆造纸研究院,北京,100102;2.制浆造纸国家工程实验室,北京,100102 
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Abstract:
      Lightly cross-linked amphoteric polyacrylamide (AmPAM) was synthesized by the aqueous solution copolymerization method using acrylamide (AM), 2-methacryloxyethyl trimethyl ammonium chloride (DMC) and acrylic acid (AA) as monomers, N-methylolacrylamide (NMA) as molecular structure modification additive. The strengthening effect of AmPAM was also studied.The results showed that the optimal polymerization conditions were: n(AM)∶n(DMC)∶n(AA)=8.0∶1.5∶0.5, the mass fraction of monomer was 20%, the dosage of initiator was 0.4%, the reaction temperature was 80℃, the reaction time was 5 h, the dosage of NMA was 3% respectively. Meanwhile, the strengthening effect of the lab-made AmPAM applied in paper was better than that of the commercial linear AmPAM products with the same addition.
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