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Improvement of Reactivity of Viscose-grade Dissolving Pulp by Cellulase Treatment
  
DOI:10.11981/j.issn.1000-6842.2017.04.1
Key Words:viscose; dissolving pulp; reactivity; viscosity; specific surface area
Fund Project:福建省自然科学基金面上项目(2015J01074);福建省教育厅科技计划项目(JA15171);江苏省制浆造纸科学与技术重点实验室开放基金资助项目(201518)。
Author NameAffiliation
李亚丽1,3 1.福建农林大学材料工程学院,福建福州,350002;3.山东仁丰特种材料股份有限公司,山东桓台,256407 
黄六莲1 1.福建农林大学材料工程学院,福建福州,350002 
陈礼辉1 1.福建农林大学材料工程学院,福建福州,350002 
苗庆显1,2,* 1.福建农林大学材料工程学院,福建福州,350002;2.南京林业大学江苏省制浆造纸科学与技术重点实验室,江苏南京,210037 
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Abstract:
      The cellulase was used to treat the viscose-grade dissolving pulp. The effect of enzymatic treatment on the reactivity, viscosity, fiber morphology, degree of crystallinity, pore diameter and specific surface area of the pulp was investigated. The fiber surface morphology was also observed by scanning electron microscope. The results showed that the reactivity of dissolving pulp could be obviously improved by cellulase treatment. The optimized treatment process was as follows: enzyme dosage 0.08 IU/g o.d. pulp, treating time 15 min, temperature 55℃, and pH value of 5.0. Under the optimized conditions, the Fock reactivity was increased by 27.6%, and the viscose filtering perfor-mance was improved from no pass to successful pass. Compared with the control sample, enzymatic treatment led to the slight decline of viscosity of the pulp and molecular weight of cellulose, and the pore diameter and specific surface area of dissolving pulp fiber increased dramatically. The peeling phenomenon and pores on the fiber surface were also clearly observed, but the fiber morphology was basically unchanged.
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