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Removal of Bromate Using Nanoscale Zero-valent Iron Supported on Spherical Lignin
  
DOI:10.11981/j.issn.1000-6842.2018.01.7
Key Words:spherical lignin; bromate; nanoscale zero-valent iron; adsorption; removal
Fund Project:国家自然科学基金面上基金资助项目(No.21577018)。
Author NameAffiliation
刘 畅 福州大学环境与资源学院,福建福州,350116 
刘明华* 福州大学环境与资源学院,福建福州,350116 
刘以凡 福州大学环境与资源学院,福建福州,350116 
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Abstract:
      In order to remove the tracebromate in drinking water, nanoscale zero-valent iron supported on spherical lignin (LSAC-Fe) was synthesized through liquid-phase reduction method using spherical cyanoethyl lignin as raw material.The LSAC-Fe was characterized by field emission scanning electron microscopy (FESEM), X-ray diffractometer (XRD), X-ray photoelectron spectroscopy (XPS) and nitrogen adsorption (BET). The adsorption effect of LSAC-Fe on BrO-3 under different conditions was investigated, and the thermodynamic adsorption and removal mechanism were studied. The results showed that the nanoscale zero-valent iron was distributed homogeneously on the spherical lignin, and LSAC-Fe had a high surface activity. The removal percentage of BrO-3 decreased with the increase of the initial pH of the solution of and the initial concentration of BrO-3. The BrO-3adsorption process of LSAC-Fe was the endothermic process, and the temperature rise was beneficial to the adsorption of BrO-3 on LSAC-Fe.
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