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Identification of Refractory Organics in Pulping and Papermaking Waste Water Using Wheat Straw Pulp as Raw Material |
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DOI:10.11981/j.issn.1000-6842.2018.04.12 |
Key Words:wheat straw pulp; waste water; refractory organics; CODCr; GC-MS; UV254 |
Fund Project:陕西省教育厅专项科研计划项目(No.18JK1021)。 |
Author Name | Affiliation | SONG Xiao-qiao1,* | 1.Xi’an University of Architecture and Technology Huaqing College, Xi’an, Shaanxi Province, 710043 | LIU Gang2 | 2.Shaanxi Hailan Environmental Protection Technology Co., Ltd., Xi’an, Shaanxi Province, 710043 | LI Tian-xin3 | 3.School of Civil and Environmental Engineering, Beijing University of Science and Technology, Beijing, 100083 | SONG Shao-hua1 | 1.Xi’an University of Architecture and Technology Huaqing College, Xi’an, Shaanxi Province, 710043 |
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Abstract: |
The CODCr concentration of papermaking waste water using wheat straw pulp as raw material is still rather higher after treating with the coagulation-nuclear flocculation process mainly due to its difficult biodegradability, the residual CODCr in the treated waste water always is a difficult problem. To explore its causes, pre- and post-treatment waste water were analyzed by GC-MS and UV254. The results showed that, small molecules organic contaminants remained in the water was the main reason causing high CODCr, such as 1,2-benzenedicarboxylic acid, bis(2-methylpropyl) ester and 1,2-benzenedicarboxylic acid, mono(2-ethylhexyl) ester. The results also indirectly indicated that the combination process had good effect on the refractory aromatic macromolecule organic pollutants, and could improve biodegradability of the waste water. |
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