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Study on Preparation of Sodium Carboxymethyl Cellulose/Adipic Dihydrazide Hydrogel and Its Adsorption Performance for Heavy Metal Ions
Received:December 28, 2020  
DOI:10.11981/j.issn.1000-6842.2021.04.38
Key Words:sodium carboxymethyl cellulose (CMC);adipic dihydrazide (ADH);hydrogel;heavy metal ions;wastewater
Author NameAffiliationPostcode
YUAN Qi School of Chemistry and Food Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410114 410114
WANG Yulong School of Chemistry and Food Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410114 410114
HAN Junyuan School of Chemistry and Food Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410114 410114
WEI Xinxin School of Chemistry and Food Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410114 410114
DAI Yang School of Chemistry and Food Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410114 410114
LIU Yanxin School of Chemistry and Food Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410114 410114
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Abstract:
      The sodium carboxymethyl cellulose/adipic dihydrazide (CMC/ADH) hydrogel with three-dimensional network structure was successfully prepared by using CMC as the substrate and ADH as the cross-linking agent. The adsorption performance of the CMC/ADH hydrogel on heavy metal ions (Cr6+, Cu2+, and Pb2+) in wastewater was studied. The as-prepared hydrogel was characterized through Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), X-ray energy spectrum analysis (EDS), and swelling performance analysis. The effects of adsorption time, pH value, and initial concentration of heavy metal ion on the adsorption process of CMC/ADH hydrogel in simulated wastewater, and the mechanism of which were studied. The results showed that the adsorption capacities of CMC/ADH hydrogel for Cr6+, Cu2+, and Pb2+ were 31.5, 75.9, and 72.0 mg/g, respectively, at room temperature (25℃), pH value of 3, initial concentration of heavy metal ion of 50 mg/L, and adsorption time of 300 min. The kinetic model and isothermal model fitting results of the adsorption process showed that adsorption of CMC/ADH hydrogel on heavy metal ions was a monolayer chemical process.
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