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Research Progress of Cellulose/Rare-earth Hybrid Photoluminescent Materials
Received:April 25, 2022  
DOI:10.11981/j.issn.1000-6842.2023.02.114
Key Words:cellulose;rare-earth ion;hybrid material;fluorescence
Author NameAffiliationPostcode
CAO Hui Tianjin Key Lab of Pulp and Paper, Tianjin University of Science & Technology, Tianjin, 300457 300457
JIA Lingyun Tianjin Key Lab of Pulp and Paper, Tianjin University of Science & Technology, Tianjin, 300457 300457
LIU Wenli Tianjin Key Lab of Pulp and Paper, Tianjin University of Science & Technology, Tianjin, 300457 300457
LIU Pengtao Tianjin Key Lab of Pulp and Paper, Tianjin University of Science & Technology, Tianjin, 300457 300457
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Abstract:
      Lanthanide is a metal rare-earth element; its trivalent ion (Ln3+) is prone to coordination with nitrogen and oxygen atoms due to their unique electronic layer structure, and exhibits unique fluorescence properties. The coordination of organic ligands forms high-coordination complexes with special topological structures. However, the inherent defects such as difficulty in processing and molding, accompanying side reactions, and refractory degradation limit the practical application of rare-earth coordination compound. Therefore, it is normally composited with polymer base to fabricate hybrid materials. Compared with traditional polymers, cellulose, as a new generation of hybrid matrix base materials, has the advantages of high specific surface area, degradability, renewability, and chemical modifiability, and is gradually used as the carrier for rare-earth hybrid luminescent materials. In this review, the research progress of cellulose/rare earth hybrid materials in bioimaging, medical dressings, photoelectric conversion, fluorescence anti-counterfeiting, and fluorescent probes in recent years was summarized, and its development trend was prospected.
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