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Effect of Non-derived Solvent System and Regeneration Process on Cellulose Structure and Properties
Received:June 28, 2022  
DOI:10.11981/j.issn.1000-6842.2023.04.107
Key Words:cellulose;non-derivative solvents;regenerative solvents;regenerative temperature;regenerative humidity
Fund Project:浙江省自然科学基金(LQ21C160006);衢江区科技计划项目(QJ2020023)。
Author NameAffiliationPostcode
PAN Xinyue* Institute of Pulp and Paper Making, College of Textile Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, Zhejiang Province, 310018 310018
YANG Xiangjian Zhejiang Huafeng Paper Technology Co, LTD, Huzhou, Zhejiang Province 313300
GONG Runzhu Institute of Pulp and Paper Making, College of Textile Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, Zhejiang Province, 310018 310018
HUANG Zhonglei Institute of Pulp and Paper Making, College of Textile Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, Zhejiang Province, 310018 310018
CHEN Tianying Institute of Pulp and Paper Making, College of Textile Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, Zhejiang Province, 310018 310018
LI Bin Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, Shandong Province, 266101 266101
TANG Yanjun Institute of Pulp and Paper Making, College of Textile Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, Zhejiang Province, 310018 310018
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Abstract:
      Cellulose is the most abundant natural polymer in nature, with many advantages such as structural stability, recyclability and biodegradability. Natural cellulose polymers have high crystallinity and single function, which is difficult to be applied in a wide range and many fields. Dissolved cellulose macromolecules can be rearranged into cellulose materials with special structures and properties under specific regeneration conditions. The solvent selection and regeneration process of cellulose have a certain degree of influence on the morphology, crystal structure, crystallinity and thermal stability of regenerated cellulose. Regenerated cellulose is easy to carry out various chemical reactions, which is of great significance for expanding the application ranges of cellulose. Therefore, the effects of different non-derivative solvents and regeneration processes (regenerative solvents, regeneration temperature, regenerative humidity) on the structures and properties of regenerated cellulose was reviewed in this paper.
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