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Preparation and Properties of High-efficiency Luminescent Perovskite Quantum Dots/Nanocellulose Composite Reinforced Films
Received:August 06, 2024  Revised:September 06, 2024
DOI:10.11981/j.issn.1000-6842.2024.04.18
Key Words:perovskite quantum dots;nanocellulose;photoluminescence quantum yield;fluorescence intensity
Fund Project:国家自然科学基金(22409127);中国科学技术协会青年人才托举工程(2023QNRC0159)。
Author NameAffiliationPostcode
XING Jialong College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an, Shaanxi Province, 710021 710021
MA Cong College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an, Shaanxi Province, 710021 710021
ZHANG Jingru* College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an, Shaanxi Province, 710021 710021
ZHANG Meiyun* College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an, Shaanxi Province, 710021 710021
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Abstract:
      In this study, the inorganic CsPbBr3 quantum dots (BVA-CsPbBr3 PQDs) with uniform size, controllable morphology, and high fluorescence quantum yield (PLQY=58.1%) were synthesized by adopting the thermal injection method, and the 5-bromovaleric acid (BVA) was used to replace the oleic acid (OA) as the surface ligand in the synergic action with oleylamine (OLA). Based on that, the excellent mechanical properties and abundant porous structure of cellulose nanofibers (CNF) were combined to prepare the PQDs@CNF composite reinforced films, which enabled the BVA-CsPbBr3 PQDs to be uniformly dispersed and firmly anchored in the CNF fiber network, effectively avoiding the agglomeration of the PQDs and enhancing the mechanical strength of the PQDs@CNF composite reinforced films. The results showed that the PQDs@CNF composite reinforced films had excellent luminescence and mechanical properties, which not only retained the original high photoluminescence intensity of BVA-CsPbBr3 PQDs, but also had the environmental adaptability and stability due to the combination with CNF.
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