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Study on Antibacterial Paper Prepared by Starch-based Coating Solution Based on Orange Peel Essential Oil Emulsified with Cellulose Nanocrystalline
Received:February 19, 2024  Revised:March 23, 2024
DOI:10.11981/j.issn.1000-6842.2024.04.100
Key Words:cellulose nanocrystalline;orange peel essential oil;starch;coating;antimicrobial paper
Fund Project:湖南省自然科学基金项目(2023JJ30009);湖南省教育厅重点研究项目(22A0208)。
Author NameAffiliationPostcode
CHEN Qijie* School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410076 410076
LUO Chengyu School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410076 410076
ZHENG Xueming China CEC Engineering Corporation, Changsha, Hu’nan Province, 410114 410114
JIN Xingming Beijing Shieldry Technology Co., Ltd., Beijing, 102600 102600
YOU Na School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410076 410076
LIU Tao Hunan Guangxin Technology Co., Ltd., Shaoyang, Hu’nan Province, 422900 422900
WAN Jinming School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha, Hu’nan Province, 410076 410076
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Abstract:
      Using mung bean starch (MBS) as the substrate and citric acid as the crosslinking agent, TEMPO oxidized cellulose nanocrystalline (TOCN) was used to emulsify orange peel essential oil (OPO), and to prepare TOCN-OPO Pickering emulsion as the antibacterial agent, so as to further prepare starch-based coating solution MBS/TOCN-OPO. Then the antibacterial paper was prepared by coating MBS/TOCN-OPO on the original paper. The effect of MBS/TOCN-OPO coating amount on the strength and antibacterial properties of antibacterial paper was discussed. The results showed that compared with original paper, when the MBS/TOCN-OPO coating amount was 9 g/m2, the folding strength of antibacterial paper was increased from 9 to 60 times, the tensile index and burst index were increased by 35.0% and 42.1%, respectively, the water vapor transmission rate was decreased by 38.6%, and the water contact angle was increased to 65.42°. The antibacterial paper had the best antibacterial effect on penicillium. MBS/TOCN-OPO antibacterial paper had a good antibacterial fresh-keeping application effect when applied to packaging tomato.
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