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Carboxylated Modified Cellulose and Its Adsorption Properties for Amphetamine |
Received:December 14, 2023 Revised:January 29, 2024 |
DOI:10.11981/j.issn.1000-6842.2025.01.93 |
Key Words:cellulose;carboxylic modification;amphetamine;high performance liquid chromatography |
Fund Project:国家自然科学基金(22208057);福建省自然科学基金(2020J01506)。 |
Author Name | Affiliation | Postcode | ZHANG Rui | Department of Environment and Safety Engineering, Fuzhou University, Fuzhou, Fujian Province, 350108 | 350108 | WANG Luying | Department of Environment and Safety Engineering, Fuzhou University, Fuzhou, Fujian Province, 350108 | 350108 | HUANG jian* | Department of Environment and Safety Engineering, Fuzhou University, Fuzhou, Fujian Province, 350108 | 350108 | LIN Chunxiang* | Department of Environment and Safety Engineering, Fuzhou University, Fuzhou, Fujian Province, 350108 Fujian Provincial Engineering Research Center of Rural Waste Recycling Technology, Fuzhou, Fujian Province, 350108 | 350108 |
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Abstract: |
In this study, cellulose was used as the raw material, and it was esterified by polyacidic anhydride to prepare the carboxylated modified cellulose material (Cell-COOH).The preparation conditions of Cell-COOH were optimized through one-factor experiment, the structure of Cell-COOH was characterized, and its adsorption properties and behaviors were investigated. The results showed that the equilibrium adsorption capacity of Cell-COOH on 20 mg/L amphetamine solution was 34.59 mg/g under the conditions of cellulose to homophthalic anhydride mass ratio of 1∶3, reaction temperature of 115 ℃, and reaction time of 1.5 h. The adsorption behavior of Cell-COOH towards amphetamine was in accordance with the Langmuir isothermal model and the pseudo-second kinetic model, which was mainly single-layer-chemisorption, and the adsorption process was a self-motivated exothermic reaction. The adsorption capacity of Cell-COOH towards amphetamine was 92.64% of first adsorption after 7 cycles of adsorption-desorption experiments, showing a good stability and reusability. |
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