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Carboxylated Modified Cellulose and Its Adsorption Properties for Amphetamine
Received:December 14, 2023  Revised:January 29, 2024
DOI:10.11981/j.issn.1000-6842.2025.01.93
Key Words:cellulose;carboxylic modification;amphetamine;high performance liquid chromatography
Fund Project:国家自然科学基金(22208057);福建省自然科学基金(2020J01506)。
Author NameAffiliationPostcode
ZHANG Rui Department of Environment and Safety Engineering, Fuzhou University, Fuzhou, Fujian Province, 350108 350108
WANG Luying Department of Environment and Safety Engineering, Fuzhou University, Fuzhou, Fujian Province, 350108 350108
HUANG jian* Department of Environment and Safety Engineering, Fuzhou University, Fuzhou, Fujian Province, 350108 350108
LIN Chunxiang* Department of Environment and Safety Engineering, Fuzhou University, Fuzhou, Fujian Province, 350108
Fujian Provincial Engineering Research Center of Rural Waste Recycling Technology, Fuzhou, Fujian Province, 350108 
350108
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Abstract:
      In this study, cellulose was used as the raw material, and it was esterified by polyacidic anhydride to prepare the carboxylated modified cellulose material (Cell-COOH).The preparation conditions of Cell-COOH were optimized through one-factor experiment, the structure of Cell-COOH was characterized, and its adsorption properties and behaviors were investigated. The results showed that the equilibrium adsorption capacity of Cell-COOH on 20 mg/L amphetamine solution was 34.59 mg/g under the conditions of cellulose to homophthalic anhydride mass ratio of 1∶3, reaction temperature of 115 ℃, and reaction time of 1.5 h. The adsorption behavior of Cell-COOH towards amphetamine was in accordance with the Langmuir isothermal model and the pseudo-second kinetic model, which was mainly single-layer-chemisorption, and the adsorption process was a self-motivated exothermic reaction. The adsorption capacity of Cell-COOH towards amphetamine was 92.64% of first adsorption after 7 cycles of adsorption-desorption experiments, showing a good stability and reusability.
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