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Preparation of Enteromorpha Polysaccharides/Konjac Glucosidan/Biochar Fertilizer Mulch Film
Received:March 17, 2024  Revised:April 07, 2024
DOI:10.11981/j.issn.1000-6842.2025.01.115
Key Words:Enteromorpha polysaccharide;Konjac glucomannan;biochar;degradable mulch film;nutritional function
Fund Project:国家自然科学基金(32271821);泰山学院引进人才科研启动基金(Y-01-2021023);泰山产业领军人才工程资助。
Author NameAffiliationPostcode
LI Xiang College of Engineering, Qufu Normal University, Rizhao, Shandong Province, 276826
Shandong Binhai New Materials Technology Co., Ltd., Linyi, Shandong Province, 276600 
276600
SONG Weiguang Shandong Binhai New Materials Technology Co., Ltd., Linyi, Shandong Province, 276600
Shanghai Yinai New Material Science & Technology Co., Ltd., Shanghai, 201799 
201799
CHENG Hongyu Shanghai Yinai New Material Science & Technology Co., Ltd., Shanghai, 201799 201799
WANG Xioadi College of Chemistry and Chemical Engineering, Taishan University, Taian, Shandong Province, 271000 271000
WANG Shujie College of Engineering, Qufu Normal University, Rizhao, Shandong Province, 276826 276826
LI Qing College of Engineering, Qufu Normal University, Rizhao, Shandong Province, 276826 276826
SUN Zhonghua* College of Chemistry and Chemical Engineering, Taishan University, Taian, Shandong Province, 271000 271000
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Abstract:
      This study extracted Enteromorpha polysaccharide from Enteromorpha, and used urea-loaded biochar (U-BC, loading ratio of 17.8%), Enteromorpha polysaccharide, and konjac glucomannan (KGM) as raw materials to prepare a biodegradable nutrient-functionalized Enteromorpha polysaccharide/KGM/biochar fertilizer mulch film (UBCF). The chemical structure, urea-releasing property, mechanical properties, water resistance, light transmittance, thermal stability, and biodegradability of UBCF were systematically investigated. The results revealed that UBCF contained abundant functional groups including hydroxyl, carboxyl, and sulfonic acid groups. The cumulative release ratio of urea in UBCF was 76.9% after 20 h water immersion. Notably, UBCF exhibited light transmittance <3%, meeting the optical requirements for opaque black films. After 80 days of soil burial, the degradation rate of UBCF reached 68.3%, confirming its excellent light-blocking capability, biodegradability, and favorable thermal stability.
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