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Study on Preparation of Sodium Carboxymethyl Cellulose/Carboxymethyl Chitosan Aerogel-based Moist Electri city Generation Device and Its Performance
Received:October 28, 2025  Revised:November 19, 2025
DOI:10.11981/j.issn.1000-6842.2026.01.30
Key Words:carboxymethyl cellulose;carboxymethyl chitosan;aerogel;moist electricity generation devices (MEGs)
Fund Project:陕西科技大学自然科学前沿研究基金(2020XSGG-07);陕西省重点研发计划(2022GY-278);陕西省自然科学基础研究计划(2023-JC-YB-104);广西清洁化制浆造纸与污染控制重点实验室开放基金(2023GXZZKF36)。
Author NameAffiliationPostcode
XIANG Zhong* College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an, Shaanxi Province, 710021 710021
TIAN Xiuzhi College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an, Shaanxi Province, 710021 710021
LI Yuhang College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an, Shaanxi Province, 710021 710021
JIAO Xinye College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an, Shaanxi Province, 710021 710021
DU Yichun College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an, Shaanxi Province, 710021 710021
JIANG Xue* College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an, Shaanxi Province, 710021 710021
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Abstract:
      In this study, carboxymethyl cellulose sodium (CMC-Na) and carboxymethyl chitosan (CMCS) were used as raw materials to prepare CMC-Na/CMCS aerogel. Then the aerogel was assembled with a porous aluminum mesh and copper foil to construct a novel moist electricity generation devices (MEGs) featuring a ‘sandwich’ structure that integrated both efficient moisture capture and conversion capabilities. The performance of moist electricity generation of prepared CMC-Na/CMCS aerogel-based MEGs was evaluated. The results indicated that the successful cross-linking between CMC-Na and CMCS was occurred, endowing the CMC-Na/CMCS aerogel with a three-dimensional network structure and uniform pore. Under conditions at 45 ℃ and relative humidity of 80%, the CMC-Na/CMCS aerogel-based MEGs achieved a maximum stable open-circuit voltage (Voc) of 0.90 V and a short-circuit current (Isc) of 2.6 μA. Under normal environmental conditions (temperature of 25~40 ℃, relative humidity of 55%~75%), the CMC-Na/CMCS aerogel-based MEGs sustained continuous voltage output for up to 24 h, with Voc stabilizing between 0.43 V and 0.79 V, demonstrating excellent environmental adaptability and operational stability.
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