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Study on Preparation and Properties of Nanocellulose from Bambusa Emeiensis L. via Acidic Deep Eutectic Solvent Pretreatment
Received:June 17, 2026  Revised:July 21, 2026
DOI:10.11981/j.issn.1000-6842.2026.03.32
Key Words:Bambusa emeiensis L.;deep eutectic solvent;pretreatment;lignin-containing cellulose nanofibril
Fund Project:国家自然科学基金225782212024年江苏高校“青蓝工程”项目国家自然科学基金(22578221);2024年江苏高校“青蓝工程”项目。
Author NameAffiliationPostcode
Gu Juan* 1College of Light Industry and Food Engineering, Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass Materials, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 210037
Zhang Yuefan 1College of Light Industry and Food Engineering, Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass Materials, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 210037
Zhou Xueyi 1College of Light Industry and Food Engineering, Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass Materials, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 210037
Xu Tingting 1College of Light Industry and Food Engineering, Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass Materials, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 210037
Dai Hongqi 1College of Light Industry and Food Engineering, Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass Materials, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 210037
Zhou Xuelian 2State Key Lab for Development and Utilization of Forest Food Resources, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing, Jiangsu Province, 210042 210042
Bian Huiyang* 1College of Light Industry and Food Engineering, Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass Materials, Nanjing Forestry University, Nanjing, Jiangsu Province, 210037 210037
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Abstract:
      Using Bambusa emeiensis L. as the raw material, lignin-containing cellulose nanofibril (LCNF) were prepared from it through pretreatment with a ternary acidic deep eutectic solvent (DES) composed of choline chloride, glycerol, and p-toluenesulfonic acid, followed by high-pressure homogenization. The removal behaviors of the major components of fiber from Bambusa emeiensis L. during acidic DES pretreatment were investigated, and the effects of lignin content on the physicochemical properties of LCNF were systematically evaluated. Pearson correlation analysis was further employed to quantify the relationships among the different properties. The results showed that the lignin removal rate of fiber from Bambusa emeiensis L. reached 84.7% after DES pretreatment. With decreasing lignin content, the average width of the resulting LCNF decreased from 24.47 nm to 19.95 nm, while the crystallinity index increased from 60.2% to 67.6%. The maximum thermal degradation temperature ranged from 330 ℃ to 350 ℃. The rheological analysis revealed that the LCNF suspensions exhibited shear-thinning behavior and a typical “solid-like” gel network characteristic. Pearson correlation analysis showed a strong positive correlation between lignin content and the average LCNF width (r = 0.98), and a highly negative correlation between lignin content and crystallinity index (r = -0.88).
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