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| Study on Preparation and Performance of Sandalwood Essential Oil@Chitosan/Cellulose Nanofibril Microcapsules |
| Received:December 28, 2025 Revised:January 09, 2026 |
| DOI:10.11981/j.issn.1000-6842.2026.03.80 |
| Key Words:sandalwood essential oil;cellulose nanofibril;chitosan;microcapsule;co-coagulation method |
| Fund Project:浙江景兴纸业股份有限公司校企合作项目齐鲁工业大学制浆造纸科学与技术教育部重点实验室开放基金KF202010云南中烟工业有限责任公司科技项目2024YL04云南中烟再造烟叶有限责任公司科技项目GYCXJS-02浙江景兴纸业股份有限公司校企合作项目;齐鲁工业大学制浆造纸科学与技术教育部重点实验室开放基金(KF202010);云南中烟工业有限责任公司科技项目(2024YL04);云南中烟再造烟叶有限责任公司科技项目(GYCXJS-02)。 |
| Author Name | Affiliation | Postcode | | Han Kun | 1College of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 | | Hu Mengxin | 1College of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 | | Song Jiayi | 2China National Pulp and Paper Research Institute Co., Ltd., Beijing, 100102 | 100102 | | Liu Yingying* | 1College of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 | | Wu Shijie | 3Yunnan China Tobacco Reconstituted Tobacco Co., Ltd., Kunming, Yunnan Province, 650106 | 650106 | | Liu Hongbin* | 1College of Light Industry Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457 | 300457 |
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| Abstract: |
| In this study, the co-coagulation method was employed to prepare SEO@CS/CNF microcapsules using sandalwood essential oil (SEO) as the core material, chitosan (CS) and cellulose nanofibril (CNF) as the composite shell materials, Tween-80 as the emulsifier, and sodium tripolyphosphate (TPP) as the cross-linking agent, with the aim of achieving effectively protecting SEO and controlled-release. Using the average particle size of the microcapsules and the SEO encapsulation efficiency as key evaluation indicators, the optimum process conditions for microcapsule preparation were determined to be a mass ratio CS to CNF of 8∶1, a mass ratio of the core material to the wall material of 4∶1, and a system pH value of 4.5. Under the optimum conditions, the SEO@CS/CNF microcapsules exhibited an SEO encapsulation efficiency of 94%, a zeta potential of 7.0 mV, and an average particle size of 4.4 µm. They also demonstrated excellent thermal stability and slow-release performance. After 14 days of storage in an aqueous environment, the cumulative release rate of SEO from SEO@CS/CNF microcapsules was only 55.3%. The results of the slow-release kinetics fitting indicated that the sustained-release process of SEO from SEO@CS/CNF microcapsules followed a first-order kinetic model, and the release mechanism was primarily non-conventional transport. |
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